nitro-Grela catalyst

Chemical name: (1,3-dimesitylimidazolidin-2-ylidene)(2-isopropoxy-5-nitrobenzylidene)ruthenium(VI) chloride


Product number: AS2032     |     CAS number: 502964-52-5

Patent number: PCT/EP2003/011222 and foreign equivalents apply.

 

Chemical properties

Chemical formula:

 C31H37Cl2N3O3Ru

Molecular weight:

 671.62 g/mol

Physical state:

 powder

Color:

 green

Stability:

 air and moisture stable

 

Safety information

warning
H228, H290, H302, H312, H332, H315, H319, H413

Handling & storage information

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Recommended storage temperature: 2 - 8 °C. Do not store above 25°C (77°F). Handle and store under inert gas.

Questions about the product?

 

Europe

Joanna Drygajło
Sales Manager and Technical Support
This email address is being protected from spambots. You need JavaScript enabled to view it.
Tel.: (+48) 71-798-5621

 

North America

Grazyna Szymanska, PhD
Global Business Development
This email address is being protected from spambots. You need JavaScript enabled to view it.
Cell: (+1) 781-608-5859

 

Reference list

[1] K. Grela, K.; Harutyunyan; S., Michrowska, A. "A New Highly Efficient Ruthenium Catalyst for Metathesis Reaction" Angew. Chem. Int. Ed. 2002, 41, 4038 

[2] Michrowska, A.; Bujok, R.; Harutyunyan, S.; Sashuk, V.; Dolgonos, G.; Grela, K. J. Am. Chem. Soc. 2004, 126, 9318. 

[3] T. K. Olszewski, M. Bieniek, K. Skowerski, K. Grela, Synlett, 2013, 24, 0903–0919.

 

Applications in target oriented synthesis

[4] (-)-Sekurinine: T. Honda, H. Namiki, K. Kaneda, H. Mizutani, Org. Lett. 2004, 6, 87. 

[5] (+)-Viroallosekurinine: T. Honda, H. Namiki, M. Watanabe, H. Mizutani, Tetrahedron Lett. 2004, 45, 5211. 

[6] Hexacyclinic acid and (-)- FR182877: T. Stellfeld, U. Bhatt, M. Kalesse, Org. Lett. 2004, 6, 3889. 

[7] BILN 2061 (Ciluprevir™): WO 2004/089974 A1 and T. Nicola, M. Brenner, K. Donsbach, P. Kreye, Org. Proc. Res. Devel. 2005, 9, 513. 

[8] Ripostatin B precursor: P. Winter, W. Hiller, M. Christmann, Angew. Chem. Int. Ed. 2012, 51, 3396–3400.

[9] epi-Norpandamarilactonine-A: T. Honda, M. Ushiwata, H. Mizutani, Tetrahedron Lett. 2006, 47, 6251. 

[10] Ricciocarpin A: A. Michrowska, B. List, Nature Chemistry 2009, 1, 225

[11] Virydiofungine analogues: S. M. Goldup, C. J. Pilkington, A. J. P. White, A. Burton, A. G. M. Barrett, J. Org. Chem. 2006, 71, 6185.

[12] Porphyrin-fullerene dyad: S. Ostrowski, A. Mikus, Mol. Divers. 2003, 6, 315. 

[13] Quinine derivative: A. L. Garner, K. Koide Org. Lett., 2007, 9, 5235.

[14] Cepham analoques: J. Frelek, P. Kowalska, M. Masnyk, A. Kazimierski, A. Korda, M. Woźnica, M. Chmielewski, F. Furche, Chem. Eur. J. 2007, 23, 6732. 

[15] (+)-FR901464: B. J. Albert, A. Sivaramakrishnan, T. Naka, K. Koide, J. Am. Chem. Soc. 2006, 128, 2792.

[16] Largazole: T. Seiser, F. Kamena, N. Cramer, Angew. Chem. Int. Ed. 2008, 47, 6483.

 

Other applications:

[17] ROMP ruthenium polymerization catalysts: J. O. Krause, O. Nuyken, M. R. Buchmeiser, Chem. Eur. J. 2004, 10, 2029.

[18] ADMET polymerization of 1,4-divinylbenzenes: H. Weychardt, H. Plenio, Organometallics 2008, 27, 1479.

 

AquaMet catalyst

Chemical name: (1,3-bis(2,6-diisopropylphenyl)imidazolidin-2-ylidene)(2-((1-(methoxy(methyl)amino)-1-oxopropan-2-yl)oxy)benzylidene)ruthenium(VI) chloride


Product number: AS2038     |     CAS number: 1414707-08-6

Patent number: PCT/EP2013/053967 and foreign equivalents apply.

 

Chemical properties

Chemical formula:

C39H55Cl3N4ORu

Molecular weight:

803.31 g/mol

Physical state:

 powder

Color:

 green

Stability:

 air and moisture stable

 

Safety information

warning
H228, H290, H302, H312, H332, H315, H319, H413

Handling & storage information

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Recommended storage temperature: 2 - 8 °C. Do not store above 25°C (77°F). Handle and store under inert gas.

Questions about the product?

 

Europe

Joanna Drygajło
Sales Manager and Technical Support
This email address is being protected from spambots. You need JavaScript enabled to view it.
Tel.: (+48) 71-798-5621

 

North America

Grazyna Szymanska, PhD
Global Business Development
This email address is being protected from spambots. You need JavaScript enabled to view it.
Cell: (+1) 781-608-5859

 

Reference list

K. Skowerski, G. Szczepaniak, C. Wierzbicka, Ł. Gułajski, M. Bieniek, K. Grela Catal. Sci. Technol., 2(12), 2424 – 2427, (2012).  More

 

Examples of application

 

 

 

 

GreenCat catalyst

Chemical name: (1,3-bis(2,6-diisopropylphenyl)imidazolidin-2-ylidene)(2-((1-(methoxy(methyl)amino)-1-oxopropan-2-yl)oxy)benzylidene)ruthenium(VI) chloride


Product number: AS2034     |     CAS number: 1448663-06-6

Patent number: PCT/EP2013/062435 and foreign equivalents apply.

 

Chemical properties

Chemical formula:

C39H53Cl2N3O3Ru

Molecular weight:

783.83 g/mol

Physical state:

 powder

Color:

 green

Stability:

 air and moisture stable

 

Safety information

warning
H228, H290, H302, H312, H332, H315, H319, H413

Handling & storage information

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Recommended storage temperature: 2 - 8 °C. Do not store above 25°C (77°F). Handle and store under inert gas.

Questions about the product?

 

Europe

Joanna Drygajło
Sales Manager and Technical Support
This email address is being protected from spambots. You need JavaScript enabled to view it.
Tel.: (+48) 71-798-5621

 

North America

Grazyna Szymanska, PhD
Global Business Development
This email address is being protected from spambots. You need JavaScript enabled to view it.
Cell: (+1) 781-608-5859

 

Reference list

K. Skowerski, P. Kasprzycki, M. Bieniek, T. K. Olszewski Tetrahedron 69, 7408 – 7415 (2013). More

 

Examples of application

 

 

 

 

 

StickyCat CI catalyst

Chemical name: [1,3-Bis(2,4,6-trimethylphenyl)-4-[(trimethylammonio)methyl]imidazolidin-2-ylidene]-(2-i-propoxy-5-nitrobenzylidene)dichlororuthenium(VI) chloride


Product number: AS2047     |     CAS number: 1415661-43-6

Patent number: PCT/EP2013/053967 and foreign equivalents apply.

 

Chemical properties

Chemical formula:

C35H48Cl2IN3ORu

Molecular weight:

825.66 g/mol

Physical state:

 powder

Color:

 green

Stability:

 air and moisture stable

 

Safety information

warning
H228, H290, H302, H312, H332, H315, H319, H413

Handling & storage information

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Recommended storage temperature: 2 - 8 °C. Do not store above 25°C (77°F). Handle and store under inert gas.

Questions about the product?

 

Europe

Joanna Drygajło
Sales Manager and Technical Support
This email address is being protected from spambots. You need JavaScript enabled to view it.
Tel.: (+48) 71-798-5621

 

North America

Grazyna Szymanska, PhD
Global Business Development
This email address is being protected from spambots. You need JavaScript enabled to view it.
Cell: (+1) 781-608-5859

 

Reference list

K. Skowerski, C. Wierzbicka, G. Szczepaniak, Ł. Gułajaski, M. Bieniek, K. Grela Green Chem., 14(12), 3264 – 3268, (2012). More

 

Examples of application

 

 

 

LatMet catalyst

Chemical name: (1,3-Bis(2,4,6-trimethylphenylimidazolidin-2-ylidene)(tricyclohexylphosphine)-(2-oxobenzylidene)ruthenium(VI) dichloride


Product number: AS2035     |     CAS number: 1407229-58-6

Patent number: PCT/EP2013/065839 and foreign equivalents apply.

 

Chemical properties

Chemical formula:

C46H65ClN2OPRu

Molecular weight:

829.52 g/mol

Physical state:

 powder

Color:

 green

Stability:

 air and moisture stable

 

Safety information

warning
H228, H290, H302, H312, H332, H315, H319, H413

Handling & storage information

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Recommended storage temperature: 2 - 8 °C. Do not store above 25°C (77°F). Handle and store under inert gas.

Questions about the product?

 

Europe

Joanna Drygajło
Sales Manager and Technical Support
This email address is being protected from spambots. You need JavaScript enabled to view it.
Tel.: (+48) 71-798-5621

 

North America

Grazyna Szymanska, PhD
Global Business Development
This email address is being protected from spambots. You need JavaScript enabled to view it.
Cell: (+1) 781-608-5859

 

Reference list

A. Kozłowska, M. Dranka, M. Zachara, E. Pump, C. Slugovc, K. Skowerski, K. Grela Chem. Eur. J., 20(43), 14120 – 14125 (2014). More

 

Examples of application

 

 

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Contacts:

• Europe
Joanna Drygajło
Sales Manager and Technical Support
joanna.drygajlo@apeiron-synthesis.com
Tel.: (+48) 71-798-5621

• North America
Grazyna Szymanska, PhD
Global Business Development
grazyna.szymanska@apeiron-synthesis.com
Cell: (+1) 781-608-5859

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