nitro-Grela katalizator

Chemical name: (1,3-dimesitylimidazolidin-2-ylidene)(2-isopropoxy-5-nitrobenzylidene)ruthenium(VI) chloride


Product number: AS2032     |     CAS number: 502964-52-5

Patent number: PCT/EP2003/011222 and foreign equivalents apply.

 

Chemical properties

Chemical formula:

 C31H37Cl2N3O3Ru

Molecular weight:

 671.62 g/mol

Physical state:

 powder

Color:

 green

Stability:

 air and moisture stable

 

Safety information

warning
H228, H290, H302, H312, H332, H315, H319, H413

Handling & storage information

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Recommended storage temperature: 2 - 8 °C. Do not store above 25°C (77°F). Handle and store under inert gas.

Questions about the product?

 

Europe

Joanna Drygajło
Sales Manager and Technical Support
This email address is being protected from spambots. You need JavaScript enabled to view it.
Tel.: (+48) 71-798-5621

 

North America

Grazyna Szymanska, PhD
Global Business Development
This email address is being protected from spambots. You need JavaScript enabled to view it.
Cell: (+1) 781-608-5859

 

Reference list

[1] K. Grela, K.; Harutyunyan; S., Michrowska, A. "A New Highly Efficient Ruthenium Catalyst for Metathesis Reaction" Angew. Chem. Int. Ed. 2002, 41, 4038 

[2] Michrowska, A.; Bujok, R.; Harutyunyan, S.; Sashuk, V.; Dolgonos, G.; Grela, K. J. Am. Chem. Soc. 2004, 126, 9318. 

[3] T. K. Olszewski, M. Bieniek, K. Skowerski, K. Grela, Synlett, 2013, 24, 0903–0919.

 

Applications in target oriented synthesis

[4] (-)-Sekurinine: T. Honda, H. Namiki, K. Kaneda, H. Mizutani, Org. Lett. 2004, 6, 87. 

[5] (+)-Viroallosekurinine: T. Honda, H. Namiki, M. Watanabe, H. Mizutani, Tetrahedron Lett. 2004, 45, 5211. 

[6] Hexacyclinic acid and (-)- FR182877: T. Stellfeld, U. Bhatt, M. Kalesse, Org. Lett. 2004, 6, 3889. 

[7] BILN 2061 (Ciluprevir™): WO 2004/089974 A1 and T. Nicola, M. Brenner, K. Donsbach, P. Kreye, Org. Proc. Res. Devel. 2005, 9, 513. 

[8] Ripostatin B precursor: P. Winter, W. Hiller, M. Christmann, Angew. Chem. Int. Ed. 2012, 51, 3396–3400.

[9] epi-Norpandamarilactonine-A: T. Honda, M. Ushiwata, H. Mizutani, Tetrahedron Lett. 2006, 47, 6251. 

[10] Ricciocarpin A: A. Michrowska, B. List, Nature Chemistry 2009, 1, 225

[11] Virydiofungine analogues: S. M. Goldup, C. J. Pilkington, A. J. P. White, A. Burton, A. G. M. Barrett, J. Org. Chem. 2006, 71, 6185.

[12] Porphyrin-fullerene dyad: S. Ostrowski, A. Mikus, Mol. Divers. 2003, 6, 315. 

[13] Quinine derivative: A. L. Garner, K. Koide Org. Lett., 2007, 9, 5235.

[14] Cepham analoques: J. Frelek, P. Kowalska, M. Masnyk, A. Kazimierski, A. Korda, M. Woźnica, M. Chmielewski, F. Furche, Chem. Eur. J. 2007, 23, 6732. 

[15] (+)-FR901464: B. J. Albert, A. Sivaramakrishnan, T. Naka, K. Koide, J. Am. Chem. Soc. 2006, 128, 2792.

[16] Largazole: T. Seiser, F. Kamena, N. Cramer, Angew. Chem. Int. Ed. 2008, 47, 6483.

 

Other applications:

[17] ROMP ruthenium polymerization catalysts: J. O. Krause, O. Nuyken, M. R. Buchmeiser, Chem. Eur. J. 2004, 10, 2029.

[18] ADMET polymerization of 1,4-divinylbenzenes: H. Weychardt, H. Plenio, Organometallics 2008, 27, 1479.

 

Kontakt:

• Europa
Joanna Drygajło
Menedżer ds. sprzedaży i obsługi klienta
joanna.drygajlo@apeiron-synthesis.com
Tel.: (+48) 71-798-5621

• Ameryka Północna
dr Grazyna Szymanska
Global Business Development
grazyna.szymanska@apeiron-synthesis.com
Tel. kom.: (+1) 781-608-5859

Nasze projekty badawcze są wspierane finansowo przez